Consider a commutative ring $R$
and a simplicial map, $X\mathop {\longrightarrow }\limits ^{\pi }K,$
of finite simplicial complexes. The simplicial cochain complex of $X$
with $R$
coefficients, $\Delta ^*X,$
then has the structure of an $(R,K)$
chain complex, in the sense of Ranicki . Therefore it has a Ranicki-dual $(R,K)$
chain complex, $T \Delta ^*X$
. This (contravariant) duality functor $T:\mathcal {B} R_K\to \mathcal {B} R_K$
was defined algebraically on the category of $(R,K)$
chain complexes and $(R,K)$
chain maps.
Our main theorem, 8.1, provides a natural $(R,K)$
chain isomorphism:\[ T\Delta^*X\cong C(X_K) \]
where $C(X_K)$
is the cellular chain complex of a CW complex $X_K$
. The complex $X_K$
is a (nonsimplicial) subdivision of the complex $X$
. The $(R,K)$
structure on $C(X_K)$
arises geometrically.