In this chapter contextual probabilistic entanglement is represented withinthe Hilbert space formalism. The notion of entanglement is clarified anddemystified through decoupling it from the tensor product structure andtreating it as a constraint posed by probabilistic dependence of quantum observablesA and B. In this framework, it is meaningless to speak aboutentanglement without pointing to the fixed observables A and B, so thisis AB-entanglement. Dependence of quantum observables is formalized asnon-coincidence of conditional probabilities. Starting with this probabilisticdefinition, we achieve the Hilbert space characterization of the AB-entangledstates as amplitude non-factorisable states. In the tensor productcase, AB-entanglement implies standard entanglement, but not vice versa.AB-entanglement for dichotomous observables is equivalent to their correlation. Finally, observables entanglement is compared with dependence of random variables in classical probability theory.

According to quantum mechanics, the information with respect to any measurement on a physical system is contained in a mathematical object, the wave function. In this chapter we become familiar with the mathematical objects that represent the measured properties themselves, namely the quantum mechanical operators. We start from a brief introduction into operators and their properties, emphasizing linear operators, and noncommuting operators. Then we introduce the canonical position and momentum operators. Defining functions of operators, we derive different quantum mechanical operators that correspond to different physical observables, including angular momentum, kinetic energy, and the scalar potential energy. Finally, we introduce the quantum mechanical total energy operator (the Hamiltonian) and demonstrate its explicit generic form for nanoscale building blocks such as atoms and molecules.