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The Influence of Morphological Aspects in the Reaction Pathway and Superconductive Properties of Bi2223-Ca2CuO3 Ceramic Composites

Published online by Cambridge University Press:  21 February 2011

H. Miao ,
V. Primo ,
R. Ibañez ,
F. Sapiña ,
A. Beltran  and
D. Beltran
H. Miao
Affiliation:
UIBCM, Departament de Química Inorgánica, Facultat de Química, Universität de Valencia, Dr.Moliner 50, 46100-Burjassot (Valencia), Spain.
V. Primo
Affiliation:
UIBCM, Departament de Química Inorgánica, Facultat de Química, Universität de Valencia, Dr.Moliner 50, 46100-Burjassot (Valencia), Spain.
R. Ibañez
Affiliation:
UIBCM, Departament de Química Inorgánica, Facultat de Química, Universität de Valencia, Dr.Moliner 50, 46100-Burjassot (Valencia), Spain.
F. Sapiña
Affiliation:
UIBCM, Departament de Química Inorgánica, Facultat de Química, Universität de Valencia, Dr.Moliner 50, 46100-Burjassot (Valencia), Spain.
A. Beltran
Affiliation:
UIBCM, Departament de Química Inorgánica, Facultat de Química, Universität de Valencia, Dr.Moliner 50, 46100-Burjassot (Valencia), Spain.
D. Beltran
Affiliation:
UIBCM, Departament de Química Inorgánica, Facultat de Química, Universität de Valencia, Dr.Moliner 50, 46100-Burjassot (Valencia), Spain.
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Abstract

A variation of the solid-state matrix technique has been developed as a procedure for the preparation of 2223 bismuth superconducting phases [(Bi,Pb)2Sr2Ca1-nCunO4+2n, n=3]. The adequate processing of samples of nominal compositions 2223+x 0021, obtained both by this procedure and by the polymer matrix method, has allowed the modification of the microstructure of the calcium copper excess, with no noticeable change in that of the 2223 grains. The study of the phase evolution in the processing of the samples has shown that the formation rate of the 2223 phase is faster when the particle size of the calcium cuprate is smaller. A dependence of the intergranular superconducting properties on the secondary phase is observed, appearing as a maximum in Jc0/μcer at x=0.2 and x=0.5 for samples prepared by solid state matrix and polymer matrix methods, respectively.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 346: Symposium N – Better Ceramics Through Chemistry VI , 1994 , 427
Copyright
Copyright © Materials Research Society 1998

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References

REFERENCES

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