Published online by Cambridge University Press: 28 February 2011
GaAs-on-Si structures have been grown by atmospheric-pressure metalorganic chemical vapor deposition (MOCVD); in some samples, the GaAs nucleation layer was deposited by atomic layer epitaxy (ALE). Material quality has been characterized by Nomarski microscopy, time-resolved photoluminescence, trans- mission electron microscopy, and the performance of photovoltaic devices. The minority-carrier lifetime has been correlated with defect density and growth parameters. The use of a thermal-cycle-growth technique is seen to be a major factor in improving GaAs-on-Si material quality without resorting to the use of thick buffer layers.