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Synthesis Approaches For Improving the Nonlinear Optical Properties of Pbz Polymers

Published online by Cambridge University Press:  25 February 2011

James F. Wolfe ,
Bock H. Loo ,
Robert A. Sanderson  and
Steven P. Bitler
James F. Wolfe
Affiliation:
Chemistry Laboratory, SRI International, 333 Ravenswood Ave., Menlo Park, CA 94025
Bock H. Loo
Affiliation:
Chemistry Laboratory, SRI International, 333 Ravenswood Ave., Menlo Park, CA 94025
Robert A. Sanderson
Affiliation:
Chemistry Laboratory, SRI International, 333 Ravenswood Ave., Menlo Park, CA 94025
Steven P. Bitler
Affiliation:
Chemistry Laboratory, SRI International, 333 Ravenswood Ave., Menlo Park, CA 94025
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Abstract

The synthesis of three types of functionalized benzazole structures is described. A centrosymmetric dihydroxy-benzobisthiazole has been synthesized for incorporation in flexible polymers having rigid, conjugated, third order nlo active units in the main chain. Benzazole structures terminated with an N,N-dimethylamino group and a carboxyl group have been synthesized for use as second order nlo pendants with flexible polymers. Benzazole structures terminated with an N,N-dimethylamino group and an amino group have been synthesized as precursors to second order nlo guest molecules.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 109: Symposium K – Nonlinear Optical Properties of Polymers , 1987 , 291
Copyright
Copyright © Materials Research Society 1988

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References

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