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Effect of Calcination Temperature on the Structure of Chitosan-Modified Montmorillonites and their Adsorption of Aflatoxin B1

Published online by Cambridge University Press:  01 January 2024

Chi Lian ,
Gaofeng Wang ,
WenQiang Lv ,
Zhiming Sun  and
Shuilin Zheng
Chi Lian
Affiliation:
School of Chemical and Environmental Engineering, China University of Mining and Technology (Beijing), Beijing 100083, China
Gaofeng Wang
Affiliation:
School of Chemical and Environmental Engineering, China University of Mining and Technology (Beijing), Beijing 100083, China
WenQiang Lv
Affiliation:
School of Chemical and Environmental Engineering, China University of Mining and Technology (Beijing), Beijing 100083, China
Zhiming Sun*
Affiliation:
School of Chemical and Environmental Engineering, China University of Mining and Technology (Beijing), Beijing 100083, China
Shuilin Zheng
Affiliation:
School of Chemical and Environmental Engineering, China University of Mining and Technology (Beijing), Beijing 100083, China
*
*E-mail address of corresponding author: [email protected]
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Abstract

Chitosan (CTS) modified montmorillonite (Mnt) composites (CTS-Mnt), which have been widely reported for the adsorption of heavy-metal ions and biological dyes, have not been applied to the field of mycotoxin adsorption. The current study was focused on the preparation of CTS-Mnt by calcination as a mycotoxin adsorbent for the efficient removal of aflatoxin B1 (AFB1). The CTS-Mnt samples obtained were characterized using X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and nitrogen adsorption/desorption analysis. The CTS-Mnt samples prepared at various calcination temperatures exhibited varying structural configurations, surface hydrophobicities, and texture properties. The results revealed that stable CTS-Mnt speciments, obtained at <350°C, displayed superior adsorption capacity for AFB1 from a simulated gastrointestinal tract, increasing from 0.51 mg/g of raw Mnt to 4.97 mg/g. With increased calcination temperature, the effect of pH on the adsorption process of AFB1 becomes negligible. This study demonstrates that the novel CTS-Mnt has tremendous potential as an AFB1 adsorbent.

Keywords

AdsorptionAflatoxin B1ChitosanMontmorillonite
Type
Article
Information
Clays and Clay Minerals , Volume 67 , Issue 4 , August 2019 , pp. 357 - 366
Copyright
Copyright © Clay Minerals Society 2019

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Footnotes

This paper was originally presented during the World Forum on Industrial Minerals, held in Qing Yang, China, October 2018

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