Hostname: page-component-669899f699-b58lm Total loading time: 0 Render date: 2025-05-01T04:45:11.628Z Has data issue: false hasContentIssue false
  • English
  • Français

Bentonite/Magnetite Composite for Removal of Nitrofurazone

Published online by Cambridge University Press:  01 January 2024

Olga V. Alekseeva ,
Anna N. Rodionova ,
Andrew V. Noskov Open the ORCID record for Andrew V. Noskov [Opens in a new window]  and
Alexander V. Agafonov
Olga V. Alekseeva
Affiliation:
G.A. Krestov Institute of Solution Chemistry, Russian Academy of Sciences, Akademicheskaya str., 1, Ivanovo 153045, Russia
Anna N. Rodionova
Affiliation:
G.A. Krestov Institute of Solution Chemistry, Russian Academy of Sciences, Akademicheskaya str., 1, Ivanovo 153045, Russia
Andrew V. Noskov*
Affiliation:
G.A. Krestov Institute of Solution Chemistry, Russian Academy of Sciences, Akademicheskaya str., 1, Ivanovo 153045, Russia
Alexander V. Agafonov
Affiliation:
G.A. Krestov Institute of Solution Chemistry, Russian Academy of Sciences, Akademicheskaya str., 1, Ivanovo 153045, Russia
*
*E-mail address of corresponding author: [email protected]
Get access Rights & Permissions [Opens in a new window]

Abstract

The presence of pharmaceutical pollutants in the environment is one of the most pressing environmental problems. Adsorption from solution is an effective way to remove pharmaceuticals from liquid media, but the problem then is to separate the adsorbent from the liquids. The objective of the present study was to remove nitrofurazone from aqueous solutions using a bentonite/magnetite composite, prepared by co-precipitation of magnetite with bentonite, which could then be collected by magnetic separation. The bentonite/magnetite composite was characterized using diverse techniques, such as X-ray diffraction, scanning electron microscopy, low-temperature N2 adsorption/desorption, laser diffraction, and magnetization measurements. The particle size of the composite material did not exceed 50 μm and the particle size distribution was mono-modal with a maximum at 3.2 μm. The strong hysteresis in the magnetization curve revealed that the bentonite/magnetite particles were ferromagnetic. Adsorption of nitrofurazone by the bentonite/magnetite composite from aqueous solutions was measured and the amount of nitrofurazone adsorbed was 3.2×10–2 mmol/g. The adsorption kinetics of nitrofurazone to the bentonite/magnetite composite followed a pseudo-second-order kinetics equation. Upon adsorption, hydrogen bonds were formed between the amide groups of nitrofurazone and oxygen groups in bentonite.

Keywords

AdsorptionBentonite/magnetite CompositesIR spectroscopyMagnetic PropertiesNitrofurazoneX-ray diffraction
Type
Article
Information
Clays and Clay Minerals , Volume 67 , Issue 6 , December 2019 , pp. 471 - 480
Copyright
Copyright © Clay Minerals Society 2019

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Article purchase

Temporarily unavailable

References

Abidi, N., Duplay, J., Jada, A., Errais, E., Ghazi, M., Semhi, K., & Trabelsi-Ayadi, M. (2019). Removal of anionic dye from textile industries' effluents by using Tunisian clays as adsorbents. Zeta potential and streaming-induced potential measurements. Comptes Rendus Chimie, 22, 113–125.CrossRefGoogle Scholar
Alekseeva, O. V., Rodionova, A. N., Bagrovskaya, N. A., Agafonov, A. V., & Noskov, A. V. (2017). Effect of the organobentonite filler on structure and properties of composites based on hydroxyethyl cellulose. Journal of Chemistry, 2017, 1603937.CrossRefGoogle Scholar
Alekseeva, O. V., Rodionova, A. N., Bagrovskaya, N. A., Agafonov, A. V., & Noskov, A. V. (2019). Effect of the bentonite filler on structure and properties of composites based on hydroxyethyl cellulose. Arabian Journal of Chemistry, 12, 398–404.CrossRefGoogle Scholar
ALOthman, Z. A. (2012). A review: Fundamental aspects of silicate mesoporous materials. Materials, 5, 2874–2902.CrossRefGoogle Scholar
Barraqué, F., Montes, M. L., Fernández, M. A., Mercader, R. C., Candal, R. J., & Sánchez, R. M. T. (2018). Synthesis and characterization of magnetic-montmorillonite and magneticorgano-montmorillonite: Surface sites involved on cobalt sorption. Journal of Magnetism and Magnetic Materials, 466, 376–384.CrossRefGoogle Scholar
Bee, S.-L., Abdullah, M. A. A., Bee, S.-T., Sin, L. T., & Rahmat, A. R. (2018). Polymer nanocomposites based on silylated-montmorillonite: A review. Progress in Polymer Science, 85, 57–82.CrossRefGoogle Scholar
Biosic, M., Skoric, I., Beganovic, J., & Babic, S. (2017). Nitrofurantoin hydrolytic degradation in the environment. Chemosphere, 186, 660–668.CrossRefGoogle ScholarPubMed
Cazetta, A. L., Vargas, A. M. M., Nogami, E. M., Kunita, M. H., Guilherme, M. R., Martins, A. C., Silva, T. L., Moraes, J. C. G., & Almeida, V. C. (2011). NaOH-activated carbon of high surface area produced from coconut shell: Kinetics and equilibrium studies from the methylene blue adsorption. Chemical Engineering Journal, 174, 117–125.CrossRefGoogle Scholar
Datta, S. M. (2013). Clay–polymer nanocomposites as a novel drug carrier: Synthesis, characterization and controlled release study of Propranolol Hydrochloride. Applied Clay Science, 80–81, 85–92.Google Scholar
Deng, L., Yuan, P., Liu, D., Annabi-Bergaya, F., Zhou, J., Chen, F., & Liu, Z. (2017). Effects of microstructure of clay minerals, montmorillonite, kaolinite and halloysite, on their benzene adsorption behaviors. Applied Clay Science, 143, 184–191.CrossRefGoogle Scholar
Dordio, A. V., Miranda, S., Ramalho, J. P. P., & Carvalho, A. J. P. (2017). Mechanisms of removal of three widespread pharmaceuticals by two clay materials. Journal of Hazardous Materials, 323(Part A), 575–583.CrossRefGoogle ScholarPubMed
Gamba, M., Kovář, P., Pospíšil, M., & Sánchez, R. M. T. (2017). Insight into thiabendazole interaction with montmorillonite and organically modified montmorillonites. Applied Clay Science, 137, 59–68.CrossRefGoogle Scholar
Gil, A., Korili, S. A., & Vicente, M. A. (2008). Recent advances in the control and characterization of the porous structure of pillared clay catalysts. Catalysis Reviews, 50, 153–221.CrossRefGoogle Scholar
Golubeva, O. Y. (2016). Effect of synthesis conditions on hydrothermal crystallization, textural characteristics and morphology of aluminum-magnesium montmorillonite. Microporous and Mesoporous Materials, 224, 271–276.CrossRefGoogle Scholar
Grenni, P., Ancona, V., & Caracciolo, A. B. (2018). Ecological effects of antibiotics on natural ecosystems: A review. Microchemical Journal, 136, 25–39.CrossRefGoogle Scholar
Ho, Y.-S. (2004). Citation review of Lagergren kinetic rate equation on adsorption reactions. Scientometrics, 59, 171–177.Google Scholar
Jaynes, W. F., & Boyd, S. A. (1991). Clay mineral type and organic compound sorption by hexadecyltrimethlyammonium-exchanged clays. Soil Science Society of America Journal, 55, 43–48.CrossRefGoogle Scholar
Khashirova, S. Y., Musaev, Y., Mikitaev, A. K., Malkanduev, Y. A., & Ligidov, M. K. (2009). Hybrid nanocomposites based on guanidine methacrylate monomer and polymer and layered aluminosilicates: Synthesis, structure and properties. Polymer Science. Series B, 51, 377–382.CrossRefGoogle Scholar
Lee, C. H., Kato, M., & Usuki, A. (2011). Preparation and properties of bio-based polycarbonate/clay nanocomposites. Journal of Materials Chemistry, 21, 6844–6847.CrossRefGoogle Scholar
Liao, M. H., & Chen, D. H. (2002). Preparation and characterization of a novel magnetic nano-adsorbent. Journal of Materials Chemistry, 12, 3654–3659.CrossRefGoogle Scholar
Lin, S., Zhou, T., & Yin, S. (2017). Properties of thermally treated granular montmorillonite-palygorskite adsorbent (GMPA) and use to remove Pb2+ and Cu2+ from aqueous solutions. Clays and Clay Minerals, 65, 184–192.CrossRefGoogle Scholar
Lou, Z., Zhou, Z., Zhang, W., Zhang, X., Hu, X., Liu, P., & Zhang, H. (2015). Magnetized bentonite by Fe3O4 nanoparticles treated as adsorbent for methylene blue removal from aqueous solution: Synthesis, characterization, mechanism, kinetics and regeneration. Journal of the Taiwan Institute of Chemical Engineers, 49, 199–205.CrossRefGoogle Scholar
Ma, M., Zhang, Y., Yu, W., Shen, H., Zhang, H., & Gu, N. (2003). Preparation and characterization of magnetite nanoparticles coated by amino silane. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 212, 219–226.CrossRefGoogle Scholar
Martinez-Costa, J. I., Leyva-Ramos, R., & Padilla-Ortega, E. (2018). Sorption of diclofenac from aqueous solution on an organobentonite and adsorption of cadmium on organobentonite saturated with diclofenac. Clays and Clay Minerals, 66, 515–528.CrossRefGoogle Scholar
Park, K. W., Jung, J. H., Kim, J. D., Kim, S. K., & Kwon, O. Y. (2009). Preparation of mesoporous silica-pillared H+-titanosilicates. Microporous and Mesoporous Materials, 118, 100–105.CrossRefGoogle Scholar
Pastukhov, A. V., Davankov, V. A., Lubentsova, K. I., Kosandrovich, E. G., & Soldatov, V. S. (2013). Structure and properties of magnetic composite sorbents based on hypercrosslinked polystyrenes. Russian Journal of Physical Chemistry A, 87, 1702–1708.CrossRefGoogle Scholar
Ruiz-Hitzky, E., Aranda, P., Dardera, M., & Rytwo, G. (2010). Hybrid materials based on clays for environmental and biomedical applications. Journal of Materials Chemistry, 20, 9306–9321.CrossRefGoogle Scholar
Sahnoun, S., Boutahala, M., Tiar, C., & Kahoul, A. (2018). Adsorption of tartrazine from an aqueous solution by octadecyltrimethylammonium bromide-modified bentonite: Kinetics and isotherm modeling. Comptes Rendus Chimie, 21, 391–398.CrossRefGoogle Scholar
Sebayang, P., Kurniawan, C., Aryanto, D., Setiadi, E. A., Tamba, K., Djuhana, , & Sudiro, T. (2018). Preparation of Fe3O4/bentonite nano-composite from natural iron sand by co-precipitation method for adsorbents materials. IOP Conference Series: Materials Science and Engineering, 316, 012053.CrossRefGoogle Scholar
Yu, W. H., Li, N., Tong, D. S., Zhou, C. H., Lin, C. X., & Xu, C. Y. (2013). Adsorption of proteins and nucleic acids on clay minerals and their interactions: A review. Applied Clay Science, 80–81, 443–452.CrossRefGoogle Scholar
Zhang, W. H., Ding, Y. J., Boyd, S. A., Teppen, B. J., & Li, H. (2010). Sorption and desorption of carbamazepine from water by smectite clays. Chemosphere, 81, 954–960.CrossRefGoogle ScholarPubMed
Zhou, C. H., Shen, Z. F., Liu, L. H., & Liu, S. M. (2011). Preparation and functionality of clay-containing films. Journal of Materials Chemistry, 21, 15132–15153.CrossRefGoogle Scholar