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The kinetics and mechanisms of using cationic surfactants to reduce the dissolution of clay minerals

Published online by Cambridge University Press:  07 April 2025

Jie Li ,
YuEn Guo ,
Zhixiang Niu Open the ORCID record for Zhixiang Niu [Opens in a new window] ,
Na Li ,
Yanling Cao ,
Haishun Yin ,
Lijie Jin ,
Guoming Sun ,
Li Guo  and
Chongying Li
Jie Li
Affiliation:
NO.1 Geological Team of Shandong Provincial Bureau of Geology and Mineral Resources, Jinan, China
YuEn Guo
Affiliation:
Chengdu University of Technology, College of Materials and Chemistry & Chemical Engineering, Chengdu, China
Zhixiang Niu*
Affiliation:
NO.1 Geological Team of Shandong Provincial Bureau of Geology and Mineral Resources, Jinan, China
Na Li
Affiliation:
Chengdu University of Technology, College of Energy, Chengdu, China
Yanling Cao
Affiliation:
NO.1 Geological Team of Shandong Provincial Bureau of Geology and Mineral Resources, Jinan, China
Haishun Yin
Affiliation:
NO.1 Geological Team of Shandong Provincial Bureau of Geology and Mineral Resources, Jinan, China
Lijie Jin
Affiliation:
Jinan Petrochemical Design Institute, Jinan, China
Guoming Sun
Affiliation:
NO.1 Geological Team of Shandong Provincial Bureau of Geology and Mineral Resources, Jinan, China
Li Guo
Affiliation:
NO.1 Geological Team of Shandong Provincial Bureau of Geology and Mineral Resources, Jinan, China
Chongying Li
Affiliation:
Chengdu University of Technology, College of Materials and Chemistry & Chemical Engineering, Chengdu, China
*
Corresponding Author: Zhixiang Niu; Email: [email protected]
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Abstract

The dissolution kinetics occurring on clay minerals are influenced by various factors, including pH, temperature and mineral lattice structure. However, the influence of the surfactant is rarely studied. In the present work, cationic surfactants were investigated in terms of the dissolution of clay minerals in acidic environments. Kaolinite was selected as the representative clay mineral. The cationic surfactant inhibited the dissolution of clay minerals because it limited the attack of H+ on the kaolinite surface and then inhibited the dissolution of kaolinite by modifying the hydrophilicity of the kaolinite surface towards hydrophobicity. The inhibition ability of the surfactant might be related to its molecular structure and the type of acid used in dissolution experiments.

Keywords

Cationic surfactantsdissolution kineticskaolinitemodificationsurface control
Type
Article
Information
Clay Minerals , First View , pp. 1 - 10
Copyright
© The Author(s), 2025. Published by Cambridge University Press on behalf of The Mineralogical Society of the United Kingdom and Ireland.

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Footnotes

Associate Editor: Chun-Hui Zhou

References

Belver, C., Bañares Muñoz, M.A. & Vicente, M.A. (2002) Chemical activation of a kaoliniteite under acid and alkaline conditions. Chemistry of Materials, 14, 2033–2043.Google Scholar
Bergaya, F., Jaber, M. & Lambert, J.F. (2011) Clays and clay minerals. Pp. 1–44 in: Rubber–Clay Nanocomposites: Science, Technology, and Applications (Galimberti, M., editor). Wiley, Hoboken, NJ, USA.Google Scholar
Berner, R.A. (1978) Rate control of mineral dissolution under Earth surface conditions. American Journal of Science, 278, 1235–1252.Google Scholar
Bibi, I., Singh, B. & Silvester, E. (2014) Dissolution kinetics of soil clays in sulfuric acid solutions: ionic strength and temperature effects. Applied Geochemistry, 51, 170–183.Google Scholar
Cama, J. & Ganor, J. (2015) Dissolution kinetics of clay minerals. Pp. 101–153 in: Developments in Clay Science, vol. 6 (Tournassat, C., Steefel, C.I., Bourg, I.C. & Bergaya, F., editors). Elsevier, Amsterdam, The Netherlands.Google Scholar
Ganor, J., Mogollón, J.L & Lasaga, A.C. (1995) The effect of pH on kaoliniteite dissolution rates and on activation energy. Geochimica et Cosmochimica Acta, 59, 1037–1052.Google Scholar
Golubev, S.V., Bauer, A. & Pokrovsky, O.S. (2006) Effect of pH and organic ligands on the kinetics of smectite dissolution at 25°C. Geochimica et Cosmochimica Acta, 70, 4436–4451.Google Scholar
Hue, K.-A.A., El-Midany, A.A. & El-Shall, H.E. (2019) Adsorption/desorption stability of TCMA-modified clay in simulated digestion environment. International Journal of Environmental Research, 13, 879–885.Google Scholar
Kalam, S., Abu-Khamsin, S.A., Kamal, M.S. & Patil, S. (2021) Surfactant adsorption isotherms: a review. ACS Omega, 6, 32342–32348.Google Scholar
Khawmee, K., Suddhiprakarn, A., Kheoruenromne, I., Bibi, I. & Singh, B. (2013) Dissolution behaviour of soil kaoliniteites in acidic solutions. Clay Minerals, 48, 447–461.Google Scholar
Köhler, S.J., Dufaud, F. & Oelkers, E.H. (2003) An experimental study of illite dissolution kinetics as a function of pH from 1.4 to 12.4 and temperature from 5 to 50°C. Geochimica et Cosmochimica Acta, 67, 3583–3594.Google Scholar
Li, F.R., Zhang, H.D. & Li, C.Y. (2021) Research progress on mechanism and application of surfactant modified clay. Zhejiang Chemical Industry, 52, .Google Scholar
Migahed, M.A., Abd-El-Raouf, M., Al-Sabagh, A.M. & Abd-El-Bary, H.M. (2005) Effectiveness of some non ionic surfactants as corrosion inhibitors for carbon steel pipelines in oil fields. Electrochimica Acta, 50, 4683–4689.Google Scholar
Morse, J.W. & Arvidson, R.S. (2002). The dissolution kinetics of major sedimentary carbonate minerals. Earth-Science Reviews, 58(1), 51-84. https://doi.org/10.1016/S0012-8252(01)00083-6Google Scholar
Nagy, K.L. & Lasaga, A.C. (1992) Dissolution and precipitation kinetics of gibbsite at 80°C and pH 3: the dependence on solution saturation state. Geochimica et Cosmochimica Acta, 56, 3093–3111.Google Scholar
Rozalen, M., Huertas, F.J. & Brady, P.V. (2009) Experimental study of the effect of pH and temperature on the kinetics of montmorillonite dissolution. Geochimica et Cosmochimica Acta, 73, 3752–3766.Google Scholar
Rs, A. & Svca, B. (2021) Atomic scale mechanism of clay minerals dissolution revealed by ab initio simulations. Geochimica et Cosmochimica Acta, 293, 438–460.Google Scholar
Wieland, E. & Stumm, W. (1992) Dissolution kinetics of kaoliniteite in acidic aqueous solutions at 25°C. Geochimica et Cosmochimica Acta, 56, 3339–3355.Google Scholar
Yang, L. & Steefel, C.I. (2008) Kaoliniteite dissolution and precipitation kinetics at 22°C and pH 4. Geochimica et Cosmochimica Acta, 72, 99–116.Google Scholar
Yin, Y.M., Zhao, L.L. & Gao, T. (2021) Molecular adsorption and dissolution of magnesium olivine surface based on molecular dynamics. Journal of Southeast University (Natural Science Edition), 51, 121–128.Google Scholar
Zhao, S.G., Zhong, H. & Liu, G. (2007) Effect of quaternary ammonium salts on flotation behavior of aluminosilicate minerals. Journal of Central South University of Technology, 14, 500–503.Google Scholar